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Phosphogypsum circular economy considerations: A critical …

Approximately 58% of the PG are stacked, 28% are discharged in coastal waters and only 14% are further processed. This critical review provides an overview of the physical-chemical properties of PG produced from sedimentary and magmatic …

EPA Approves Use of Phosphogypsum in Road Construction

WASHINGTON (October 14, 2020) — Today, U.S. Environmental Protection Agency (EPA) Administrator Andrew Wheeler approved a request from The Fertilizer Institute (TFI) to allow phosphogypsum to be used in government road construction projects. "Allowing the reuse of phosphogypsum shows EPA's commitment to working with industry in a way that …

Phosphogypsum: Properties and Potential Use in …

Phosphogypsum: Properties and Potential Use in Agriculture M. Barka Outbakat, Redouane Choukr-Allah, Moussa Bouray, Mohamed EL Gharous, and Khalil EL Mejahed ... other hand, the production cost in the dry process is much higher. However, the acid produced with the dry process is pure (Al-Fariss et al. 1992). Fig. 1 . Diagram of the …

Collaborative Utilization Status of Red Mud and Phosphogypsum…

Red mud and phosphogypsum are the solid waste byproducts of the alumina and phosphoric acid production processes, respectively. Their global annual production has reached 1.1–12 billion tons and 150–200 million tons, respectively [1,2,3,4,5,6].Globally, the total amount of red mud produced every year is between 60 …

Sen. Marshall Introduces Bill to Sustain the Long-Term …

(Washington, D.C., November 18, 2022) – U.S. Senator Roger Marshall, M.D. today announced introduction of the Fertilizer Stewardship, Utilization, Sustainability, Technology, Access, Innovation, and Nourishment (Fertilizer SUSTAIN) Act to strengthen our domestic fertilizer industry and ensure that American growers have access to the crop nutrients …

Study of the physical-chemical properties of the Moroccan phosphogypsum …

The production of phosphoric acid in the world generates an enormous amount of a by-product named phosphogypsum (PG). A large quantity of this PG is stockpiled or dumped into environment, causing ...

Radioactive Material From Fertilizer Production | US EPA

The EPA has regulated phosphogypsum since 1989. The EPA requires phosphogypsum to be placed in stacks. All uses of phosphogypsum waste have been banned unless the waste has very little radioactivity. TENORM: Fertilizer and Fertilizer Production Wastes This webpage provides information on fertilizer and fertilizer …

2020 World Phosphate Rock Production …

Phosphogypsum also continues to receive attention; the industrial by-product of phosphoric acid production is currently stored in stacks, but has drawn interest as a potential resource, with opportunities for use as a …

(PDF) Phosphogypsum Processing Method

The comparison of the developed phosphogypsum processing method with well-known national and foreign analogues showed that its cost-efficiency is 2-3 times higher; the area necessary for the plant ...

Phosphogypsum: A Review of the Florida Institute of …

Phosphogypsum disposal was a very simple matter in the early days of the industry. If at all possible, you located your plant near the ocean or on a river and dumped the phosphogypsum into the sea or the river. If you were foolish enough to locate where water disposal was not possible, you suffered the economic penalty of having to stack the ...

Valorization of phosphogypsum in cement-based materials…

Phosphogypsum is an industrial by-product resulting from the production of phosphoric acid by ''wet acid method" [14]. This material is generated from chemical reaction between phosphate rock (Ca 10 (PO 4 ) 6 F 2 ), sulphuric acid and water, as described Equation (1) ([ 15, 16 ]).

Phosphogypsum: Properties and Potential Use in Agriculture

Phosphogypsum (PG) is a calcium sulphate dihydrate and a by-product of the phosphate fertilizer industry. It is produced in huge quantities (300 MT/year), but only 15% of the PG produced is recycled. ... Define the effects of PG on crop production, soil, water, and the environment. Phosphogypsum contains some heavy metals and radioactive ...

Effect of Surfactants on Phosphogypsum Crystallization and Filtration

Abstract. A nonionic surfactant (CMR-100) containing a mixture of C 6 –C 22 sorbitan esters was tested to improve the filtration rate of phosphogypsum produced from a South Florida phosphate concentrate at different sulfate levels. Tests were carried out on a lab-scale under operating conditions that simulate, to a large extent, the industrial …

Study on The Production of Ammonium Sulfate Fertlizer …

The production of ammonium sulfate fert ilizer from phosphogypsum is studied. The phosphogypsum is considered by prod uct from extraction process of sulphoric acid. The mereseberg process is used a waste of phosphogypsum with ammonium carbonate to produce ammonium sulfate as a main product and calcium carbonate as a byproduct. It …

TENORM: Fertilizer and Fertilizer Production Wastes

About 90 percent of domestic production capacity in Florida, North Carolina, and Tennessee. Florida alone accounts for approximately 80 percent of the current capacity, making it the world's largest phosphate producing area. ... Side view of phosphogypsum stack. Phosphate production generates huge amounts of …

Comprehensive Utilization of Phosphogypsum and …

Phosphogypsum is a by-product of phosphoric acid industrial production, and its stacking volume is increasing year by year, which brings a great threat to the environment and agricultural safety. The way of comprehensive utilization of phosphogypsum was described, and the mechanism of phosphogypsum producing …

Properties, Purification, and Applications of Phosphogypsum: …

Phosphogypsum (PG) is a by-product produced during the wet process of phosphoric acid (H 3 PO 4) production from natural phosphate rocks. Approximately …

Sustainable Utilization of Phosphogypsum in Multi …

Findings indicate that aggregates containing 70% phosphogypsum can effectively meet the requirements for C25 concrete applications, underscoring the method's sustainability through efficient …

Exploring the potential reuse of phosphogypsum: A waste or …

Phosphogypsum (PG), the main industrial by-product of phosphate fertilizer industry, primarily consists of calcium sulfate dihydrate. However, it contains various …

Production Waste Management: Qualitative and …

Phosphogypsum (PG: CaSO4·2H2O) is a waste product (or by-product) from the production of phosphoric acid, the main component in the production of concentrated simple and complex fertilizers. The world production of phosphogypsum exceeds 200 million tons per year. PG discharged into water bodies (seas, rivers) or …

Realising the circular phosphorus economy delivers for …

During the process of phosphoric acid production, the potentially hazardous waste by-product phosphogypsum, hydrated calcium sulfate, is produced at a quantity 5-times that of phosphoric acid 110,143.

EVALUATION OF POTENTIAL COMMERCIAL PROCESSES …

PRODUCTION OF SULFURIC ACID FROM PHOSPHOGYPSUM FINAL REPORT By ZELLARS-WILLIAMS, INC. P. O, Box 2008 Lakeland, Florida 33806 - 2008 ... product phosphogypsum in nations which lack domestic gypsum sources and seek to avoid expensive imports are absent in Florida. As a result, phosphoric acid ...

Use of an industrial by-product phosphogypsum in the production …

Dihydrate phosphogypsum (PG) is the main by-product of the production of fertilizers in SC Lifosa (Lithuania). The specific gravity of phosphogypsum is 2360 kg/m 3, its average pH value is 3.1.The XRD pattern of this material (Fig. 1, curve a) confirms that the dominant compound is dihydrate gypsum CaSO 4 ⋅2H 2 O (d – 0.763, 0.428, 0.306, …

Omani gypsum exports rise in 2022

Oman: Producers and exporters despatched 9.9Mt of gypsum from Oman in 2022. The figure corresponds to year-on-year growth of 13% from 8.74Mt in 2021. The Oman Daily Observer newspaper has …

The Development of a New Phosphogypsum-Based …

The annual production of phosphogypsum in Tunisia is currently estimated to be 10 million tons. Its storage in slag in close proximity to production plants generates pollution problems; however, valorization may be a solution. The present paper proposes a simple process for the valorization of this by-product into a construction material.

Gypsum Data Sheet

Domestic Production and Use: In 2019, domestic production of crude gypsum was estimated to be 20 million tons with a value of about $160 million. The leading crude …

Application of phosphogypsum in soilization: a review

Phosphogypsum(PG) CaSO 4 ·2H 2 O is a by-product of phosphate ore processing, phosphate fertilizer and compound fertilizer containing phosphorus, and wet phosphoric acid production, which is acidic (pH = 1–4.5) and poorly mobile (Zirnea et al. 2013).The reaction of PG generated in the wet process of phosphoric acid production …

Phosphogypsum: potential uses and problems – a …

Phosphogypsum could be used as a substitute of natural gypsum in the production of Portland cement to control the hydration reaction rate of cement. In this study, raw phosphogypsum was...

The Use of By-Product Phosphogypsum for Road Bases …

In 1979 Japan was producing phosphogypsum at a rate of 2.748 million metric tons per year (4). In Flor­ ida, more than 334 million tons of phosphogypsum had been stockpiled as of 1980. At that time, Florida's phosphogypsum production was 33 million tons per year. Long-term projections predict that more than 1

Phosphogypsum impacts on soil chemical properties and

Phosphogypsum (PG) is a by-product of phosphorus fertilizer that is typically stacked near production sites. Phosphogypsum contains trace elements and naturally occurring radioactive materials which may be hazardous to the surrounding environment. Phosphogypsum stack reclamation typically involves placing a soil cap …

Agricultural Uses of Phosphogypsum, Gypsum, and Ca …

Phosphogypsum Phosphogypsum is a byproduct of the phosphate fertilizer industry and emanates from the production of phosphoric acid from rock phosphate. Production of phosphogypsum in Florida is estimated to be 27.2 million Mg annually (Hunter 1989). The composition of phosphogypsum varies depending upon the source

Phosphogypsum: Properties and Potential Use in Agriculture

Phosphogypsum (PG) is a calcium sulphate dihydrate and a by-product of the phosphate fertilizer industry. It is produced in huge quantities (300 MT/year), but only 15% of the …

(PDF) Moroccan Phosphogypsum: Complete …

The production of phosphogypsum has significantly . increased as a result of recent phosphate industry advance-ments in China, India, and several other nations with quickl y .

Effective and innovative procedures to use phosphogypsum …

Phosphogypsum (PG) waste is a by-product generated from wet-process phosphoric acid (H3PO4) manufacturing during phosphate rock decomposition. Worldwide, the annual production of PG ranges between 100 and 300 million tons, with only a few quantities utilized in several application domains (about 15%), the unused PG is usually …

Radioactivity and elemental composition of phosphogypsum produced …

The phosphogypsum samples in the present study exceeded the average values reported by May & Sweeney (1984) for B (up to 7 times), Ba (2-10 times), Ni (up to 13 times), Pb (4-30 times), Sr (30-94 times) and Y (22-78 times). 3.4 Gamma-emitting radionuclides The concentration of Ra-226 within phosphogypsum is a concern …

The possibility of the phosphogypsum use in the production …

Phosphogypsum (PG) is a by-product produced during the wet process of phosphoric acid (H_3PO_4) production from natural phosphate rocks. Approximately 4–6 tons of PG is produced per ton of phosphoric…

Exploring the potential reuse of phosphogypsum: A waste …

PG production rates will follow fertilizer production rates, recording a sevenfold increase by 2050 compared to 1961 rates and reaching 438 million tons per year. The total stock of PG stored in tailing ponds for the period between 1961 and 2050 will reach almost 11 billion tons by 2050 ( Nedelciu et al., 2020 ).

Phosphogypsum in the Circular Economy

4. production of phosphoric acid by the wet process 5. manufacture and use of ammonium phosphate fertilizers 6. superphosphate fertilizers 7. nitrogen phosphate fertilizers 8. animal feed phosphates 9. phosphogypsum 10. decommissioning of wet-process plants 11. extraction of uranium from phosphoric acid 12. production of phosphorus by the ...

Utilization of phosphogypsum to synthesize α-hemihydrate …

DOI: 10.1016/j.conbuildmat.2023.130453 Corpus ID: 256217243; Utilization of phosphogypsum to synthesize α-hemihydrate gypsum in H3PO4–H2O solution @article{Chen2023UtilizationOP, title={Utilization of phosphogypsum to synthesize $alpha$-hemihydrate gypsum in H3PO4–H2O solution}, author={Long Chen and Lin …

Sustainable Utilization of Phosphogypsum in …

This study contributes to sustainable construction practices by exploring the use of phosphogypsum, a commonly discarded byproduct, in the production of recycled aggregates. Addressing both …